Dielectric Studies of H-Bonded Complexes of Anilines with Alcohol

R. Priscilla, S. Balamuralikrishnan

Abstract: The Hydrogen-bonded complexes formed by aniline, o-chloro aniline, p-chloro aniline with ethanol at 303K have been determined by using Huysken?s method based on the Onsager theory. The excess dipole moments of the complexes were obtained from bond angle data available from molecular orbital theory. The enhancement of the dipole moment values confirms the hydrogen bonding between all the anilines.

Keywords: H-Bonding, Anilines, Ethanol, Dipole moment, Dipolar increment